PROTON NMR OF THE MAGNETIC TRANSITION IN TDAE-C60

Citation
R. Blinc et al., PROTON NMR OF THE MAGNETIC TRANSITION IN TDAE-C60, Solid state communications, 89(6), 1994, pp. 487-491
Citations number
10
Categorie Soggetti
Physics, Condensed Matter
Journal title
ISSN journal
00381098
Volume
89
Issue
6
Year of publication
1994
Pages
487 - 491
Database
ISI
SICI code
0038-1098(1994)89:6<487:PNOTMT>2.0.ZU;2-7
Abstract
A strongly temperature dependent paramagnetic hyperfine contact NMR sh ift which saturates below T(c) has been observed for the methyl group protons in tetrakis-dimethylamino-ethylene (TDAE+)-C60. The magnitude of the shift below T(c) is much smaller than expected if all C60 unpai red spins would order ferromagnetically. The results confirm the exist ence of a magnetic transition in TDAE-C60 and suggest that ferromagnet ically correlated clusters appear below T(c) in a sea of spin cancelle d regions.