WEAK TERNARY CT SALTS FORMED BY ALPHA-KEGGIN POLYANIONS AND TETRAPHENYLPORPHYRINATO ZN(II) IN THE PRESENCE OF HALIDE-IONS

Authors
ATTANASIO D BACHECHI F
Citation
D. Attanasio et F. Bachechi, WEAK TERNARY CT SALTS FORMED BY ALPHA-KEGGIN POLYANIONS AND TETRAPHENYLPORPHYRINATO ZN(II) IN THE PRESENCE OF HALIDE-IONS, Advanced materials, 6(2), 1994, pp. 145-147
Citations number
19
Categorie Soggetti
Material Science
Journal title
Advanced materials → ACNP
ISSN journal
09359648
Volume
6
Issue
2
Year of publication
1994
Pages
145 - 147
Database
ISI
SICI code
0935-9648(1994)6:2<145:WTCSFB>2.0.ZU;2-R
Abstract
Molecular complexes between alpha-Keggin polyanions and tetraphenylpor phyrinato Zn(II) are unexpectedly stable have been obtained in the pre sence of an ancillary donor anion such as a halide. X-ray structure de termination reveals integrated organic-inorganic stacks with alkyl amm onium cations acting as spacers. Development of these compounds, which combine thermally and photochemically redox active units, may lead to molecular materials with interesting electro- and photochromic proper ties.