Inelastic excitonic scattering processes have been investigated in ZnS
e/ZnSxSe1-x multiple-quantum-well structures of different well width a
nd strain content. The free-exciton energies have been determined by p
hotoluminescence excitation spectroscopy and compared with those calcu
lated accounting for the actual strain contribution. All the samples s
how strong luminescence related to bound or localized excitons. In str
ain relaxed samples, the interaction of these states with free-electro
ns gives rise to optical gain at low temperature. In addition, a stron
ger stimulated emission is observable up to room temperature. The temp
erature and pumping intensity dependences of this latter amplification
process suggest that two different lasing mechanisms may be invoked,
namely free-exciton-bound-exciton or free-exciton-longitudinal-optical
-phonon inelastic scattering.