TEMPERATURE-DEPENDENCE OF THE SEPARATION FACTOR FOR HYDROGEN ISOTOPESDURING ADSORPTION ON ZEOLITE NAA

Citation
Ia. Alekseev et Vd. Trenin, TEMPERATURE-DEPENDENCE OF THE SEPARATION FACTOR FOR HYDROGEN ISOTOPESDURING ADSORPTION ON ZEOLITE NAA, Russian journal of applied chemistry, 66(1), 1993, pp. 111-115
Citations number
13
Categorie Soggetti
Chemistry Applied
ISSN journal
10704272
Volume
66
Issue
1
Year of publication
1993
Part
2
Pages
111 - 115
Database
ISI
SICI code
1070-4272(1993)66:1<111:TOTSFF>2.0.ZU;2-3
Abstract
The binary separation factors for H-2-HT and D2-DT adsorption at the N aA zeolite were determined in batch equilibration experiments between 22 and 140 K. The equations for the separation factor temperature depe ndence were obtained. The experimentally obtained separation factor va lues for alpha(H-2)-HT = 69 at 22 K, and for alpha(D2)-DT = 4.3 at 25 K, are significantly higher then those obtained in liquid hydrogen fra ctionation. Absorption by NaA zeolite is proposed for concentration of tritium and its removal from hydrogen.