Ia. Alekseev et Vd. Trenin, TEMPERATURE-DEPENDENCE OF THE SEPARATION FACTOR FOR HYDROGEN ISOTOPESDURING ADSORPTION ON ZEOLITE NAA, Russian journal of applied chemistry, 66(1), 1993, pp. 111-115
The binary separation factors for H-2-HT and D2-DT adsorption at the N
aA zeolite were determined in batch equilibration experiments between
22 and 140 K. The equations for the separation factor temperature depe
ndence were obtained. The experimentally obtained separation factor va
lues for alpha(H-2)-HT = 69 at 22 K, and for alpha(D2)-DT = 4.3 at 25
K, are significantly higher then those obtained in liquid hydrogen fra
ctionation. Absorption by NaA zeolite is proposed for concentration of
tritium and its removal from hydrogen.