USE OF PARAMAGNETIC-RELAXATION REAGENTS IN NMR RELAXATION ANALYSIS OFDISPERSE SYSTEMS

Authors
GOGOLASHVILI EL DZYUBENKO NG KUZMINA NP MARGULIS BY MARTYNENKO LI
Citation
El. Gogolashvili et al., USE OF PARAMAGNETIC-RELAXATION REAGENTS IN NMR RELAXATION ANALYSIS OFDISPERSE SYSTEMS, Russian journal of applied chemistry, 66(1), 1993, pp. 116-120
Citations number
30
Categorie Soggetti
Chemistry Applied
Journal title
Russian journal of applied chemistry → ACNP
ISSN journal
10704272
Volume
66
Issue
1
Year of publication
1993
Part
2
Pages
116 - 120
Database
ISI
SICI code
1070-4272(1993)66:1<116:UOPRIN>2.0.ZU;2-E
Abstract
The possibility of using gadolinium(III) beta-diketonates as paramagne tic relaxation reagents in NMR relaxation analysis of emulsions of the second kind was investigated. It was shown for the adduct of gadolini um(III)tris(dipivaloylmethanate) with trioctylphosphine oxide that the hydrocarbon proton relaxation time selectively decreases when the rea gent is added to the emulsion so that phase identification is facilita ted and the precision of the analysis is increased.