FUNCTIONALIZED 1,1-ETHENEDITHIOLATES AS LIGANDS .3. PALLADIUM(II) ANDPLATINUM(II) COMPLEXES WITH FERROCENYL-SUBSTITUTED 1,1-ETHENEDITHIOLATE LIGANDS - CRYSTAL-STRUCTURE ANALYSES OF 3)P)(2)M[S2C=CH-C(O)-(ETA(5)-C5H4)FE(ETA(5)-C5H5)] (M=PD,PT)

Authors
BUCHWEITZ J GOMPPER R POLBORN K ROBL C SAILER MT WEIGAND W
Citation
J. Buchweitz et al., FUNCTIONALIZED 1,1-ETHENEDITHIOLATES AS LIGANDS .3. PALLADIUM(II) ANDPLATINUM(II) COMPLEXES WITH FERROCENYL-SUBSTITUTED 1,1-ETHENEDITHIOLATE LIGANDS - CRYSTAL-STRUCTURE ANALYSES OF 3)P)(2)M[S2C=CH-C(O)-(ETA(5)-C5H4)FE(ETA(5)-C5H5)] (M=PD,PT), Chemische Berichte, 127(1), 1994, pp. 23-26
Citations number
24
Categorie Soggetti
Chemistry
Journal title
Chemische Berichte → ACNP
ISSN journal
00092940
Volume
127
Issue
1
Year of publication
1994
Pages
23 - 26
Database
ISI
SICI code
0009-2940(1994)127:1<23:F1AL.P>2.0.ZU;2-E
Abstract
The ferrocenyl-substituted mono- (3) and 1,1'-bis-dithiocarboxylic aci ds (4) have been prepared. These acids react with L(2)MCl(2) (M=Pd,Pt; L=PEt(3), PPh(3), and 1/2 dppe) in the presence of sodium acetate to give the cis heterodi- and heterotrimetallic complexes is-L(2)M[S2C=CH -C(O)-(eta(5)-C5H4)Fe(eta(5)-C5H5)] (5a: M = Pd, L = PPh(3); 5b: M = P t, L = PPh3; 5c: M=Pt, L=1/2 dppe) and [cis-L(2)MS(2)C= CH-C(O)-(eta(5 )-C5H4)]Fe-2 (6a: M = Pd, L = PPh(3); 6b: M = Pt, L = PEt(3); 6c: M = Pt, L = PPh(3); 6d: M = Pt, L = 1/2 dppe). The structures of 5a and 5b have been determined by single-crystal X-ray diffraction.