REACTION OF DECABORANE WITH THE PHOSPHAAL KYNE PCTBU

Authors
MEYER F PAETZOLD P ENGLERT U
Citation
F. Meyer et al., REACTION OF DECABORANE WITH THE PHOSPHAAL KYNE PCTBU, Chemische Berichte, 127(1), 1994, pp. 93-95
Citations number
19
Categorie Soggetti
Chemistry
Journal title
Chemische Berichte → ACNP
ISSN journal
00092940
Volume
127
Issue
1
Year of publication
1994
Pages
93 - 95
Database
ISI
SICI code
0009-2940(1994)127:1<93:RODWTP>2.0.ZU;2-V
Abstract
The borane B10H12(SMe(2))(2) (1) reacts with the phosphaalkyne P drop CtBu to form the product [B10H11(SMe(2))][C(tBu)-PH](B10H12) (2), in w hich two B-10 units are Linked by a HP-CtBu bridge. The B-10 unit B is simply bound to the bridge C atom, whereas the B-10 unit A is bound t o both bridging atoms, P and C, by atom B6 and, moreover, to the P ato m by atom B5. The solvate complex 2 CH2 . Cl-2 crystallizes in the spa ce group $($) over bar$$ P1.