SYNTHESIS OF A POLYMER-SUPPORTED O-PHENYLENE(DIPHOSPHINE) AND CHARACTERIZATION OF SOME METAL-COMPLEXES

Authors
CHAMPNESS NR LEVASON W OLDROYD RD GULLIVER DJ
Citation
Nr. Champness et al., SYNTHESIS OF A POLYMER-SUPPORTED O-PHENYLENE(DIPHOSPHINE) AND CHARACTERIZATION OF SOME METAL-COMPLEXES, Journal of organometallic chemistry, 465(1-2), 1994, pp. 275-281
Citations number
37
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
465
Issue
1-2
Year of publication
1994
Pages
275 - 281
Database
ISI
SICI code
0022-328X(1994)465:1-2<275:SOAPOA>2.0.ZU;2-D
Abstract
The synthesis is described of the polymer-supported diphosphine, PolPP , in which an o-C6H3(PPh(2))(2) unit is linked via a -CH2O group in th e 4-position of the benzene ring to a Merrifield resin. The preparatio ns of the complexes (PolPP)NiCl2, (PolPP)PtCl2, (PolPP>Rh(PPh(3))Cl an d (PolPP)Ru(PPh(3))Cl-2 and related model compounds are reported, and their characterization by UV-visibIe spectroscopy and metal edge EXAFS is described.