N. Laidani et al., N-IMPLANTATION INDUCED ENHANCED ADHESION OF AMORPHOUS-SIC FILMS DEPOSITED ON STAINLESS-STEEL(), Applied physics letters, 64(8), 1994, pp. 977-979
Amorphous a-SiC films were deposited by rf magnetron sputtering on sta
inless steel and N+ implantations were performed at room temperature o
ver a fluence range of 1X10(16)-1X10(17) ions/cm2 at 30 and 160 keV Ch
emical characterization of the a-SiC/steel interface and compositional
depth profiles were obtained by Auger electron spectroscopy. Adhesion
properties of the films were examined using a scratch tester in conju
nction with scanning electron microscopy. A strong adhesion enhancemen
t (about a factor of eight) along with an improvement of the fracture
toughness were observed in the implanted a-SiC/steel specimens. The ke
y mechanisms envisaged to explain the enhanced adhesion is mainly rela
ted to the new chemical bondings, involving C and N in Si-(N,C)-Cr com
plexes formation at the a-SiC/steel interface.