Al/Si/GaAs(001) diode structures grown by molecular beam epitaxy were
examined as a function of the thickness of the Si interface layer and
the intensity of the As or Al flux employed during Si deposition. We f
ound that Schottky barriers as low as 0.3-0.4 eV (in the presence of a
sufficiently high As flux) or as high as 1.0-1.1 eV (in the presence
of a sufficiently high Al flux) can be established on n-type GaAs at S
i coverages in the submonolayer to monolayer range. We therefore assoc
iate the tunability of the barrier height with a Si-induced local inte
rface dipole.