ULTRATRACE ANALYSIS OF URANIUM AND THORIUM IN GLASS .1. ICP-MS, CLASSICAL PHOTOMETRY AND CHELATE-GC

Citation
U. Rohr et al., ULTRATRACE ANALYSIS OF URANIUM AND THORIUM IN GLASS .1. ICP-MS, CLASSICAL PHOTOMETRY AND CHELATE-GC, Fresenius' journal of analytical chemistry, 348(5-6), 1994, pp. 356-363
Citations number
15
Categorie Soggetti
Chemistry Analytical
ISSN journal
09370633
Volume
348
Issue
5-6
Year of publication
1994
Pages
356 - 363
Database
ISI
SICI code
0937-0633(1994)348:5-6<356:UAOUAT>2.0.ZU;2-D
Abstract
Three methods of determination for uranium and thorium traces and ultr atraces in glass were developed: a simple and powerful ICP-MS method e xhibiting limits of determination in the one ng/g-range; a complex met hod with end-determination by classical photometry and a limit of dete rmination for U and Th of 20 ng/g; and a method with chelate-complex f ormation for U and Th and subsequent GC-detection with a Ni-63-ECD wit h limits of determination in the mug/g-range. These methods are critic ally compared and tested for real type samples of special glasses.