PREPARATION OF ORGANO PALLADIUM SOLS FROM PALLADIUM COMPLEXES IN VARIOUS ALCOHOLS

Citation
K. Esumi et al., PREPARATION OF ORGANO PALLADIUM SOLS FROM PALLADIUM COMPLEXES IN VARIOUS ALCOHOLS, Colloids and surfaces. A, Physicochemical and engineering aspects, 82(1), 1994, pp. 111-113
Citations number
22
Categorie Soggetti
Chemistry Physical
ISSN journal
09277757
Volume
82
Issue
1
Year of publication
1994
Pages
111 - 113
Database
ISI
SICI code
0927-7757(1994)82:1<111:POOPSF>2.0.ZU;2-M
Abstract
Organo palladium sols were prepared from palladium complexes in variou s alcohols in the presence of polyvinylpyrrolidone. Uniform palladium particles ranging in size between 2 and 4 nm were obtained in 1-pentan ol, alpha-phenylethyl alcohol, and beta-phenylethyl alcohol solutions of palladium acetate. In contrast, Pd(acac)2 (acac, 2.4-pentanedionato ) yielded particles of wider size distribution compared to those from palladium acetate.