D-PENICILLAMINE AND DL-PENICILLAMINE COMPLEXES OF CHROMIUM(III)

Authors
HEASTER H HOGGARD PE
Citation
H. Heaster et Pe. Hoggard, D-PENICILLAMINE AND DL-PENICILLAMINE COMPLEXES OF CHROMIUM(III), Polyhedron, 13(3), 1994, pp. 333-337
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
13
Issue
3
Year of publication
1994
Pages
333 - 337
Database
ISI
SICI code
0277-5387(1994)13:3<333:DADCOC>2.0.ZU;2-G
Abstract
An angular overlap model analysis was performed on the electronic spec trum of [Cr(D-pen)(2)](-) and [Cr(D-pen)(L-pen)](-) (H(2)pen = penicil lamine), in both of which penicillamine acts as a tridentate ligand. T he D-penicillamine complex has the trans-S, cis-N, cis-O configuration , while the DL-penicillamine complex has the cis-S, cis-N, cis-O confi guration. The carboxylate group is a strong pi-donor and the deprotona ted sulphydryl a moderate pi-donor.