EMR LINEWIDTH ANALYSIS OF CHCL3 SOLUTION OF BIS(ETHYLACETOACETATO)COPPER(II) COMPLEX

Authors
PRABHANANDA BS YORDANOV ND PATEV N
Citation
Bs. Prabhananda et al., EMR LINEWIDTH ANALYSIS OF CHCL3 SOLUTION OF BIS(ETHYLACETOACETATO)COPPER(II) COMPLEX, Polyhedron, 13(3), 1994, pp. 469-474
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
13
Issue
3
Year of publication
1994
Pages
469 - 474
Database
ISI
SICI code
0277-5387(1994)13:3<469:ELAOCS>2.0.ZU;2-8
Abstract
Two copper(II) complexes in equilibrium contribute to the solution EMR (EPR) spectrum of bis(ethylacetoacetato)copper(II). In the present pa per? EMR line-widths have been analysed to obtain better insight into the nature of these two paramagnetic species. The analysis shows that the EMR anisotropy and rotational correlation times of the two paramag netic species are similar in magnitude. The EMR anisotropy determined from line-width studies is compared with that obtained from a frozen s olution EMR spectrum.