We have measured optically detected cyclotron resonance using far-infr
ared radiation on an exceptionally pure sample of GaAs in fields up to
15.5 T. This relatively new experimental technique is shown to offer
high resolution of free and donor impurity-bound electron transitions
without the reproducibility problems of photoconductivity. The data co
nfirm the existence of metastable donor states and provide a detailed
picture of chemical shifts. The optically detected cyclotron resonance
signal represents an interaction between the donor bound electron sta
tes which are influenced by the far-infrared radiation and the donor b
ound exciton states which are responsible for the photoluminescence. A
ttenuation of the luminescence intensity under far-infrared illuminati
on is primarily the result of a photothermal effect. At high fields, t
here is indication of an interaction between the electron and excitoni
c energy levels.