S-matrices associated to the vector representations of the quantum gro
ups for the classical Lie algebras are constructed. For the a(m-1) and
c(m) algebras the complete S-matrix is found by an application of the
bootstrap equations. It is shown that the simplest form for the S-mat
rix which generalizes that of the Gross-Neveu model is not consistent
for the non-simply-laced algebras due to the existence of unexplained
singularities on the physical strip. However, a form which generalizes
the S-matrix of the principal chiral model is shown to be consistent
via an argument which uses a novel application of the Coleman-Thun mec
hanism. The analysis also gives a correct description of the analytic
structure of the S-matrix of the principle chiral model for c(m).