IOWAITE, A REINVESTIGATION

Iowaite has been re-examined using new, well crystallized material fro m the Palabora open pit mine, Transvaal. Microprobe, carbon analyser a nd thermal analyses, powder and single-crystal X-ray diffraction, infr ared, UV-visible and mass spectroscopic and optical studies were made. The ideal formula is Mg6Fe2(III)(OH)16Cl2.4H2O. It is trigonal, R3mBA R, a = 3.1183(9), c = 24.113(8) angstrom, V = 203.1(2) angstrom3, Z = 3/8; D(obs) 2.09 g/cm3; D(calc) 2.04 g/cm3; hardness (Mohs) = 2 1/2. T he interlayer Cr ions are displaced from the threefold axis. It is uni axial negative, with omega = 1.561 +/- 0.002, epsilon = 1.543 +/- 0.00 2; coloured crystals are intensely pleochroic, due to intervalence cha rge transfer between the Fe3+ and Fe2+ substituting for Mg2+, with O p ale yellow, E deep blue-green.