1,2-Dimesityltettachlorodigermane 7 has been prepared by chlorination
of 1,2-dimesityldigermane 6 with CCl4. From 7, four new digermanes Mes
(CHR2)Ge(X)Ge(X)(CHR2)Mes (CHR2 = fluorenyl; X = H (4), Cl (5), OH (8)
or F (9)) have been synthesized. These sterically crowded derivatives
are obtained as two diastereoisomers which have been isolated in the
pure state by fractional crystallization. Reactions of various lithio
compounds with the chloro or fluoro derivatives 5 or 9 lead to fluoren
e, following lithium-halogen exchange and then alpha-elimination and,
in the case of (t)BuLi, a reduction of the germanium-halogen bond.