ELECTROCHEMISTRY OF OXYGENATION CATALYSTS .4. SOLVENT-COMPOSITION-DEPENDENT ISOPOTENTIAL POINTS IN CYCLIC VOLTAMMOGRAMS OF CO(SALEN)+

Authors
EICHHORN E SPEISER B
Citation
E. Eichhorn et B. Speiser, ELECTROCHEMISTRY OF OXYGENATION CATALYSTS .4. SOLVENT-COMPOSITION-DEPENDENT ISOPOTENTIAL POINTS IN CYCLIC VOLTAMMOGRAMS OF CO(SALEN)+, Journal of electroanalytical chemistry [1992], 365(1-2), 1994, pp. 207-212
Citations number
10
Categorie Soggetti
Electrochemistry,"Chemistry Analytical
Journal title
Journal of electroanalytical chemistry [1992]
ISSN journal
15726657 → ACNP
Volume
365
Issue
1-2
Year of publication
1994
Pages
207 - 212
Database
ISI
SICI code
Abstract
Isopotential points are described in multicycle voltammograms of icyli dene)ethylenediaminato-cobalt(III)perchlorate in mixtures of dimethyl formamide and pyridine. The potentials where these points occur vary w ith the solvent composition. The results are discussed in terms of the three-rung ladder scheme describing the electrode reaction with elect ron exchanges (Co(II) half arrow right over half arrow left Co(III)) a t the electrode surface and the successive exchange of two solvent mol ecules per complex.