Km. Wojcik et al., HISTORY OF DIAGENETIC FLUIDS IN A DISTANT FORELAND AREA, MIDDLE AND UPPER PENNSYLVANIAN, CHEROKEE BASIN, KANSAS, USA - FLUID INCLUSION EVIDENCE, Geochimica et cosmochimica acta, 58(3), 1994, pp. 1175-1191
Analysis of fluid inclusion data in diagenetic cements from Pennsylvan
ian limestones and sandstones of the Cherokee basin in southeastern Ka
nsas reveals the succession of diagenetic fluids in a distant foreland
of the Arkoma-Ouachita system. This succession includes early low-sal
inity (0.0-2.4 wt% NaCl eq.) fluids of meteoric affinity (Fluid I) fol
lowed by low-temperature Na-Ca-Cl brines (Fluid II with salinities bet
ween 8.4 and 24.1 wt% NaCl eq.). Fluids I and II were present in the s
ystem during precipitation of early-stage calcite cements at temperatu
res less than about 50-degrees-C. Another Na-Ca-Cl brine (Fluid III wi
th salinity up to 25 wt% NaCl eq.) was present in the system later, at
temperatures of maximum burial (at least 80-85-degrees-C) and higher.
Fluid Ill is followed by a Na-Cl brine (Fluid IV, with salinities abo
ut 19-21 wt% NaCl eq.) characterized by temperatures distinctly higher
than maximum burial, up to 150-degrees-C. Fluid III and Fluid IV were
entrapped during precipitation of late-stage baroque dolomite and Fe-
dolomite in Pennsylvanian limestones, and late-stage Fe-dolomite and a
nkerite in Pennsylvanian sandstones. The record of progression from Fl
uid III to Fluid IV may have been partially obscured by thermal re-equ
ilibriation of some inclusions during migration of Fluid IV. Fluids wi
th Na-Ca-Cl chemistry (Fluid II and III) were either indigenous subsur
face fluids of the Cherokee and Arkoma basins, or might have originate
d as reflux fluids in a Permian evaporitic basin of Central Kansas. La
ter Na-Cl brine (Fluid IV) originated in deeper parts of the Arkoma-Ou
achita system and might have acquired their salinity by dissolution of
hypothetical salts buried beneath the Ouachitas. Temperatures recorde
d by fluid inclusions in late-diagenetic carbonates are 20-60-degrees-
C higher than those calculated for the maximum burial of the studied s
ection. This thermal anomaly suggests an advective heat transfer from
the Arkoma-Ouachita system onto the shelf of the Cherokee basin relate
d to the invasion of late-diagenetic fluids.