NONLINEAR QUANTUM-MECHANICAL EFFECTS - REAL OR ARTIFACT OF INACCURATEAPPROXIMATIONS

Citation
D. Vitali et al., NONLINEAR QUANTUM-MECHANICAL EFFECTS - REAL OR ARTIFACT OF INACCURATEAPPROXIMATIONS, Chemical physics, 180(2-3), 1994, pp. 297-318
Citations number
62
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
03010104
Volume
180
Issue
2-3
Year of publication
1994
Pages
297 - 318
Database
ISI
SICI code
0301-0104(1994)180:2-3<297:NQE-RO>2.0.ZU;2-R
Abstract
We critically discuss the reliability of the discrete nonlinear Schrod inger equation (DNSE) approach in the case of a dissipative two-site s ystem. By using the Wigner pseudo-probability formalism we show that t he nonlinear effects predicted by this effective picture are generally incorrect except in the adiabatic limit with the two-site system much faster than its own thermal bath. This is the adiabatic condition opp osite to that usually adopted to derive the DNSE and a simple explanat ion of this result is given by establishing a connection between the H artree approximation and the DNSE. Theoretical arguments are provided to evaluate the error associated to the Hartree approximation, so as t o assess under which physical circumstances this key approximation is reliable.