K. Kajiyama et al., SI-O BOND FORMATION BY OXYGEN IMPLANTATION INTO SILICON, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 121(1-4), 1997, pp. 315-318
In an experiment involving implanted oxygen atoms, ready bond formatio
n with the substrate Si atoms was observed. Bond formation was confirm
ed by infrared absorption spectrum of Si-O vibration; 1100 cm(-1) asym
metric stretching mode in this experiment. O-16 or O-18 ions were impl
anted into (100) Si substrate at 90-360 keV energy with 2-15 x 10(17)/
cm(2) dose at room temperature similar to 800 degrees C. Infrared abso
rption spectrum resembled with thermal oxide one, but absorption peak
energy was a little lower with lower dose, lower implantation energy a
nd lower substrate temperature, Oxygen dose uniformity and repeatabili
ty were nondestructively monitored for SIMOX (Separation by IMplanted
OXygen) wafers which is a promising SOI (Silicon On Insulator) candida
te for integrated-circuit devices. Rutherford backscattering spectrosc
opy was utilized to calibrate dose conversion relation.