J. Taniguchi et al., UTILIZING OF HYDROCARBON CONTAMINATION FOR PREVENTION OF THE SURFACE CHARGE-UP AT ELECTRON-BEAM ASSISTED CHEMICAL ETCHING OF A DIAMOND CHIP, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 121(1-4), 1997, pp. 507-509
Electron beam assisted chemical etching (EBACE) with oxygen gas is not
applicable for direct fine patterning of diamond devices, because the
diamond is an electrical insulator and electron beam impingement of t
he diamond causes the surface charge-up. It is possible to form conduc
tive layer of hydrocarbon on the diamond surface by electron beam irra
diation in the atmosphere of diffusion pump oil vapors. In this paper,
a scanning electron microscope (SEM) combined with oxygen gas introdu
ction system was used for EBACE of the diamond. It was found by in-sit
u SEM observation that rectangular patterns with several mu m(2) area
and sub-mu m depth were formed on the diamond chip.