OZONIDE FORMATION BY TRANSANNULAR CYCLOADDITION BETWEEN A CARBONYL OXIDE AND A CARBONYL GROUP

Authors
GRIESBAUM K BALL V
Citation
K. Griesbaum et V. Ball, OZONIDE FORMATION BY TRANSANNULAR CYCLOADDITION BETWEEN A CARBONYL OXIDE AND A CARBONYL GROUP, Tetrahedron letters, 35(8), 1994, pp. 1163-1164
Citations number
4
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
8
Year of publication
1994
Pages
1163 - 1164
Database
ISI
SICI code
0040-4039(1994)35:8<1163:OFBTCB>2.0.ZU;2-S
Abstract
Ozonolysis of bicyclo[10.3.0]pentadec-1(12)-en-13-one (9a) on polyethy lene gave the corresponding ozonide 11a. The structure of the labile o zonide was proved by its transformation into the stable O-methyl oxime 11b, and by independent synthesis of 11b by ozonolysis of the O-methy l oxime of 9a.