EFFECT OF WATER ON CHEMO-SELECTIVITY AND ENDO-SELECTIVITY IN HIGH-PRESSURE DIELS-ALDER FURAN REACTIONS - HYDROPHOBIC OR POLAR EFFECTS

Authors
JENNER G
Citation
G. Jenner, EFFECT OF WATER ON CHEMO-SELECTIVITY AND ENDO-SELECTIVITY IN HIGH-PRESSURE DIELS-ALDER FURAN REACTIONS - HYDROPHOBIC OR POLAR EFFECTS, Tetrahedron letters, 35(8), 1994, pp. 1189-1192
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
8
Year of publication
1994
Pages
1189 - 1192
Database
ISI
SICI code
0040-4039(1994)35:8<1189:EOWOCA>2.0.ZU;2-X
Abstract
Diels-Alder furan additions are less sensitive to pressure in aqueous solution than in organic solvents. in some cases, water affects chemo- and stereoselectivity. The interpretation lakes into account hydropho bic as well as polar effects induced by water.