REGIOSELECTIVE AND STEREOSELECTIVE CROSS-COUPLING REACTION OF OPTICALLY-ACTIVE ALLYLSILANES - STEREOCONTROL OF PALLADIUM-MEDIATED S-E' REACTIONS

Authors
HATANAKA Y GODA K HIYAMA T
Citation
Y. Hatanaka et al., REGIOSELECTIVE AND STEREOSELECTIVE CROSS-COUPLING REACTION OF OPTICALLY-ACTIVE ALLYLSILANES - STEREOCONTROL OF PALLADIUM-MEDIATED S-E' REACTIONS, Tetrahedron letters, 35(8), 1994, pp. 1279-1282
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
8
Year of publication
1994
Pages
1279 - 1282
Database
ISI
SICI code
0040-4039(1994)35:8<1279:RASCRO>2.0.ZU;2-A
Abstract
Optically active allylsilanes undergo the gamma-regioselective cross-c oupling reactions with aryl triflates in the presence of a palladium c atalyst and a fluoride salt; the absolute configuration and % ee of th e coupled products could be controlled by the choice of the fluoride s alt and the polarity of the solvent.