A SIMPLE POLYHETEROTOPIC MOLECULAR RECEPTOR DERIVED FROM BISPYRAZOLYLMETHANE SHOWING NEGATIVE ALLOSTERIC COOPERATION OF ZN(II)

Authors
RODRIGUEZUBIS JC JUANES O BRUNET E
Citation
Jc. Rodriguezubis et al., A SIMPLE POLYHETEROTOPIC MOLECULAR RECEPTOR DERIVED FROM BISPYRAZOLYLMETHANE SHOWING NEGATIVE ALLOSTERIC COOPERATION OF ZN(II), Tetrahedron letters, 35(8), 1994, pp. 1295-1298
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
8
Year of publication
1994
Pages
1295 - 1298
Database
ISI
SICI code
0040-4039(1994)35:8<1295:ASPMRD>2.0.ZU;2-E
Abstract
The preparation of 1 as a model for negative allostery is described. T ransport experiments (bulk liquid membrane) of alkyl di- and monoammon ium cations in the presence or absence of ZnI2 in the receiving phase evidenced strong negative allosteric effects of the metal towards ammo nium complexation.