Stable carbon isotope analysis of various heavy oils and some thermo-c
atalytically converted products was performed with a thermal analyser
coupled with an isotopic ratio mass spectrometer. The temperature-prog
rammed oxidative pyroanalysis technique subdivides the classical C-13/
C-12 ratio, affording new insights into the structural composition of
heavy oils such as the contribution of naphthenoaromatics, and appears
to be of interest for following their thermal refining.