EFFECT OF GLASS COMPOSITION ON PRECIPITATION OF CRYSTALLITES IN CUCL DOPED GLASSES

Authors
KADONO K TANAKA H TARUMI T
Citation
K. Kadono et al., EFFECT OF GLASS COMPOSITION ON PRECIPITATION OF CRYSTALLITES IN CUCL DOPED GLASSES, Physics and Chemistry of Glasses, 35(1), 1994, pp. 41-43
Citations number
19
Categorie Soggetti
Material Science, Ceramics","Chemistry Physical
Journal title
Physics and Chemistry of Glasses → ACNP
ISSN journal
00319090
Volume
35
Issue
1
Year of publication
1994
Pages
41 - 43
Database
ISI
SICI code
0031-9090(1994)35:1<41:EOGCOP>2.0.ZU;2-H
Abstract
The effect of glass composition on precipitation of CuCl crystallites has been investigated for CuCl doped borosilicate and aluminoborosilic ate glasses. After annealing at various temperatures, CuCl crystallite s are observed in the glasses, the matrices of which are separated by spinodal decomposition and have a borate rich phase with high connecti vity. Furthermore, most Cu+ ions are distributed in the borate rich ph ase of these glasses. On the other hand, for glasses with a lower tend ency for phase separation, CuCl crystallites are not precipitated.