We have observed visible photoluminescence, at photon energies nearly
twice those of the usual near-infrared excitonic emissions, from thin
Si1-XGeX quantum wells at liquid He temperatures. This confirms that a
significant biexciton population is present in such samples under exc
itation conditions normally used for near-infared photo-luminescence m
easurements. The intensity of the visible luminescence increases linea
rly with excitation density, consistent with the biexcitons being loca
lized by fluctuations in alloy content. The biexciton lifetime is obse
rved to vary with the Si1-XGeX quantum well width indicating an enhanc
ement of the overlap of the particle wave functions by the quantum con
finement.