INCOHERENT QUASI-ELASTIC NEUTRON-SCATTERING STUDY OF HIGHLY ORIENTED FIBERS OF COPPER LAURATE IN THE COLUMNAR MESOPHASE

Citation
M. Bee et al., INCOHERENT QUASI-ELASTIC NEUTRON-SCATTERING STUDY OF HIGHLY ORIENTED FIBERS OF COPPER LAURATE IN THE COLUMNAR MESOPHASE, Molecular physics, 81(1), 1994, pp. 57-68
Citations number
15
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
00268976
Volume
81
Issue
1
Year of publication
1994
Pages
57 - 68
Database
ISI
SICI code
0026-8976(1994)81:1<57:IQNSOH>2.0.ZU;2-4
Abstract
Oriented fibres of dicopper tetrakis(dodecanoate) Cu-2(COOC11H23)(4) i nvestigated using the neutron backscattering technique both in the col umnar liquid crystal phase and in the crystalline phase. Differences i n the spectra recorded at various glancing angles in the columnar meso phase, on the timescale 5 x 10(-10) s, were assigned to anisotropic mo tions of the binuclear units within the columns. In the crystalline ph ase, on the 10(-10) time-scale, the fixed-window technique yielded a d etermination of the elastic incoherent structure factor.