Lr. Becerra et al., INVESTIGATION OF THE SURFACE-MORPHOLOGY OF CAPPED CDSE NANOCRYSTALLITES BY P-31 NUCLEAR-MAGNETIC-RESONANCE, The Journal of chemical physics, 100(4), 1994, pp. 3297-3300
Room temperature P-31 magic angle sample spinning (MAS) nuclear magnet
ic resonance (NMR) is used to study the phosphine chalconide species c
oordinating the surface of CdSe nanocrystallites. Two surface species
are identified: trioctylphosphine oxide (TOPO) and trioctylphosphine s
elenide (TOPSe). The TOPO coordinates Cd surface sites while trioctylp
hosphine (TOP) coordinates Se to produce surface TOPSe species. Chemic
al removal of TOPSe linkages produces CdSe nanocrystallites passivated
exclusively with TOPO. A double resonance experiment (P-31 and Se-77)
characterizes the TOPSe species. Quantitative studies indicate coordi
nation to nearly all surface Cd atoms and allows the development of a
model for the morphology of an average crystallite surface.