THE DETERMINATION OF THE 2ND DISSOCIATION-CONSTANT OF SULFURIC-ACID

Authors
LUTS P VANHEES J YPERMAN J MULLENS J VANPOUCKE LC
Citation
P. Luts et al., THE DETERMINATION OF THE 2ND DISSOCIATION-CONSTANT OF SULFURIC-ACID, Journal of solution chemistry, 23(1), 1994, pp. 75-80
Citations number
14
Categorie Soggetti
Chemistry Physical
Journal title
Journal of solution chemistry → ACNP
ISSN journal
00959782
Volume
23
Issue
1
Year of publication
1994
Pages
75 - 80
Database
ISI
SICI code
0095-9782(1994)23:1<75:TDOT2D>2.0.ZU;2-H
Abstract
The second dissociation constant of sulfuric acid is determined in 1M NaClO4 at 25-degrees-C using an electrochemical cell without liquid ju nction consisting of a glass and a perchlorate electrode. By taking in to account the association between the Na+ and SO42- ions an average v alue of 0.0184+/-0.0005 is found using three different methods. This c orresponds with an apparent acidity constant K(A2) of 0.095 +/-0.003