This paper presents a novel data processing method for thermokinetics
of first-order reactions, in which the rate constant of a first-order
reaction can be calculated from only three characteristic peak-height
data without using any peak-area, rate of temperature rise, or functio
nal table of dimensionless parameters. The saponification of ethyl ben
zoate and ethyl acetate in aqueous ethanol have been studied with a tw
in conduction calorimeter and the rate constants calculated with this
method are in fair agreement with those in the literature; hence the v
alidity of this method is demonstrated.