LIGHT-OFF BEHAVIOR OF CATALYTIC-CONVERTERS

This paper studies a system of partial differential equations modeling the behavior of an automotive catalytic converter. The particular phe nomenon considered in detail is light-off, when the temperature of the converter changes dramatically from cold to hot somewhere within the converter. The initial position of light-off and the subsequent moveme nt of this steep jump in temperature toward the inlet of the converter are analyzed. The method of matched asymptotic expansions is used to study light-off and to derive approximate formulas that determine its behavior in the limits of small heat diffusion and large activation en ergy. Numerical calculations are presented and are used to compare wit h the analytical formulas. These calculations reveal that the asymptot ic results for small diffusion are quantitatively accurate, while thos e for small diffusion and large activation energy give the qualitative behavior of the solution but give poor quantitative predictions for t he range of parameters encountered in practice.