SYNTHESIS AND ABSOLUTE STEREOSTRUCTURE OF DINAPHTH[2,1-C1',2'-E]OXEPIN-3-(5H)-ONE

Authors
BRINGMANN G HARTUNG T KROCHER O GULDEN KP LANGE J BURZLAFF H
Citation
G. Bringmann et al., SYNTHESIS AND ABSOLUTE STEREOSTRUCTURE OF DINAPHTH[2,1-C1',2'-E]OXEPIN-3-(5H)-ONE, Tetrahedron, 50(9), 1994, pp. 2831-2840
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
50
Issue
9
Year of publication
1994
Pages
2831 - 2840
Database
ISI
SICI code
0040-4020(1994)50:9<2831:SAASOD>2.0.ZU;2-R
Abstract
The synthesis, enantiomer analysis, and configurational assignment of dinaphth[2,1-c:1',2'-e]oxepin-3-(5H)-one, a seven-membered lactone-bri dged chiral binaphthalene, is reported. The elucidation of the absolut e configuration has been performed, independently by multiple scatteri ng X-ray experiments and by circular dichroism (CD).