LANTHANIDE ALKOXIDES .3. 4-COORDINATE ANIONIC NEODYMIUM(III) ALKOXIDES AND AMIDES

Authors
EDELMANN FT STEINER A STALKE D GILJE JW JAGNER S HAKANSSON M
Citation
Ft. Edelmann et al., LANTHANIDE ALKOXIDES .3. 4-COORDINATE ANIONIC NEODYMIUM(III) ALKOXIDES AND AMIDES, Polyhedron, 13(4), 1994, pp. 539-546
Citations number
37
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
13
Issue
4
Year of publication
1994
Pages
539 - 546
Database
ISI
SICI code
0277-5387(1994)13:4<539:LA.4AN>2.0.ZU;2-I
Abstract
Tetracoordinate anionic neodymium(III) alkoxides and amides are obtain ed by adduct formation of Nd[OC(tBu)3]3 (1) and Nd[N(SiMe3)2]3 (2) wit h either LiCl or LiOSiMe3. The compounds (THF)3Li(mu-Cl)Nd[OC(tBu)3]3 (3), (THF)3Li(mu-Cl)Nd [N(SiMe3)2]3 (4) and [Li(THF)4][{(Me3Si)2N}3Nd( OSiMe3)] (5) have been characterized by single-crystal X-ray analyses.