PREPARATION AND STRUCTURE OF LICYLATO-O,O')-BIS(1,5-CYCLOOCTADIENE)DIRHODIUM(I)

Authors
MIECZYNSKA E TRZECIAK AM ZIOLKOWSKI JJ LIS T
Citation
E. Mieczynska et al., PREPARATION AND STRUCTURE OF LICYLATO-O,O')-BIS(1,5-CYCLOOCTADIENE)DIRHODIUM(I), Polyhedron, 13(4), 1994, pp. 655-658
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
13
Issue
4
Year of publication
1994
Pages
655 - 658
Database
ISI
SICI code
0277-5387(1994)13:4<655:PASOL>2.0.ZU;2-#
Abstract
licylato-O,O')-bis(1,5-cyclooctadiene)dirhodium(I) complex of the form ula [Rh(HOC6H4CO2) (COD)]2 (COD = 1,5-cyclooctadiene), has been obtain ed in the reaction of [RhCl(COD)]2 with silver salicylate. It has a di meric structure with two bridging carboxylate groups, two terminally b ounded COD and Rh...Rh distance of 3.325(3) angstrom. The alpha-hydrox yl group of the salicylate ligands forms intramolecular hydrogen bondi ng with the nearest oxygen of carboxylate group.