METAL-COMPLEXES WITH BIOLOGICAL IMPORTANT LIGANDS .69. HALF-SANDWICH COMPLEXES OF COBALT(III), RHODIUM(III), IRIDIUM(III) AND RUTHENIUM(II)WITH ANIONS OF ALPHA-HYDROXYIMINO ACIDS

Authors
LAMPEKA R BERGS R KRAMER R POLBORN K BECK W
Citation
R. Lampeka et al., METAL-COMPLEXES WITH BIOLOGICAL IMPORTANT LIGANDS .69. HALF-SANDWICH COMPLEXES OF COBALT(III), RHODIUM(III), IRIDIUM(III) AND RUTHENIUM(II)WITH ANIONS OF ALPHA-HYDROXYIMINO ACIDS, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 49(2), 1994, pp. 225-232
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
49
Issue
2
Year of publication
1994
Pages
225 - 232
Database
ISI
SICI code
0932-0776(1994)49:2<225:MWBIL.>2.0.ZU;2-5
Abstract
(eta(6)-p-cymene)(Cl)Ru-N(OH)C(R)CO2 have been obtained by reactions o f (eta(5)-C(5)Me(5))Co(CO)I-2, [(eta(5)-C(5)Me(5))MCl(2)](2) (M = Rh, Ir) and [(eta(6)-p-cymene)RuCl2](2) with 2-hydroxyiminocarboxylates. T hese complexes are also accessible by template synthesis from hydroxyl amine or O-methylhydroxylamine, alpha-oxocarboxylate and (eta(5)-C(5)M e(5))Co(CO)I-2 or [(eta(5)-C(5)Me(5))MCl(2)](2) (M = Rh, Ir). The stru cture of the S-Ru enantiomer of (eta(5)-C(5)Me(5)>(I)Co-N(OH>C(CH3)CO2 has been determined by X-ray diffraction.