ENANTIOSELECTIVE AND PHOTOCATALYTIC OXIDATION OF 1,1'-BI-2-NAPHTHOL WITH A CHIRAL RUTHENIUM COMPLEX WHICH INCLUDES MOLECULAR HELICITY

Authors
HAMADA T ISHIDA H USUI S TSUMURA K OHKUBO K
Citation
T. Hamada et al., ENANTIOSELECTIVE AND PHOTOCATALYTIC OXIDATION OF 1,1'-BI-2-NAPHTHOL WITH A CHIRAL RUTHENIUM COMPLEX WHICH INCLUDES MOLECULAR HELICITY, Journal of molecular catalysis, 88(1), 1994, pp. 120000001-120000005
Citations number
6
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular catalysis → ACNP
ISSN journal
03045102
Volume
88
Issue
1
Year of publication
1994
Pages
120000001 - 120000005
Database
ISI
SICI code
0304-5102(1994)88:1<120000001:EAPOO1>2.0.ZU;2-R
Abstract
1,1'-Bi-2-naphthol was oxidized catalytically and enantioselectively ( less-than or-equal-to 15.2% e.e.), by using the chiral ruthenium compl ex, DELTA-[Ru(menbpy)3]2+ (menbpy = 4,4'-dimenthoxycarbonyl-2,2'-bipyr idine) as a photocatalyst and [Co(acac)3] (Hacac = pentane-2,4-dione) as an oxidant under photoirradiation.