SYNTHESIS OF DIISOPROPYLBENZENE OVER DEALUMINATED ZEOLITE-BETA

Citation
Pa. Parikh et al., SYNTHESIS OF DIISOPROPYLBENZENE OVER DEALUMINATED ZEOLITE-BETA, Journal of molecular catalysis, 88(1), 1994, pp. 85-92
Citations number
27
Categorie Soggetti
Chemistry Physical
ISSN journal
03045102
Volume
88
Issue
1
Year of publication
1994
Pages
85 - 92
Database
ISI
SICI code
0304-5102(1994)88:1<85:SODODZ>2.0.ZU;2-2
Abstract
Zeolite beta was used for isopropylation of cumene to diisopropylbenze nes. This zeolite deactivated with increase in time-on-stream period. To overcome the catalyst deactivation during reaction, two different s tabilization methods viz. steaming and treatment with (NH4)2SiF6 were examined. A combination of these two methods resulted in obtaining a s teady stable catalytic performance during alkylation. The effects of v arious reaction conditions on the activity/selectivity behaviour of th e stabilized zeolite have been studied.