A. Smontara et al., LOW-TEMPERATURE PHONON THERMAL-CONDUCTIVITY OF THE QUASI-ONE-DIMENSIONAL COMPOUNDS (NBSE4)3I, (TASE4)2I AND K0.3MOO3, Journal of low temperature physics, 94(3-4), 1994, pp. 289-306
We report on measurements of the thermal conductivity of quasi-one-dim
ensional compounds K0.3MoO3, (NbSe4)3I, and (TaSe4)2I between 0.07 K a
nd 4 K. Despite the presence of a charge-density wave, the observed be
haviour is similar to that expected in good insulating crystals, where
the thermal conductivity well below 1 K is mainly governed by boundar
y scattering with some degree of specular reflection. However a pronou
nced anomaly is detected in (TaSe4)2I as a sharp maximum around 1 K, f
ollowed by a broad minimum around 3 K. We ascribe this anomaly to stro
ng scattering by low-lying transverse acoustic phonons, with a very we
ak dispersion over a large part of the Brillouin zone, lying at an unu
sually low frequency.