INFLUENCE OF THE STRUCTURE AND PROPERTIES OF UNSATURATED HETEROPOLYCOMPOUNDS ON AM(III) OXIDATION AND THE STABILITY OF AM(IV) AND AM(VI)

Authors
MALIKOV DA MILYUKOVA MS MYASOEDOV BF
Citation
Da. Malikov et al., INFLUENCE OF THE STRUCTURE AND PROPERTIES OF UNSATURATED HETEROPOLYCOMPOUNDS ON AM(III) OXIDATION AND THE STABILITY OF AM(IV) AND AM(VI), Radiochemistry, 35(4), 1993, pp. 459-464
Citations number
5
Categorie Soggetti
Chemistry Analytical","Chemistry Inorganic & Nuclear
Journal title
Radiochemistry → ACNP
ISSN journal
10663622
Volume
35
Issue
4
Year of publication
1993
Pages
459 - 464
Database
ISI
SICI code
1066-3622(1993)35:4<459:IOTSAP>2.0.ZU;2-7
Abstract
The conditions for oxidation of Am(III) by a mixture of Ag+ and sodium persulfate in H2SO4 SolUtions containing the ''unsaturated' 11th orde r heteropolycompounds K7PW11O39, K8SiW11O39, K8GeW11O39, and K9BW11O39 are studied. The conditions for preparing Am(IV) and -(VI) are found and their stability is studied. This class of heteropolycompounds can be used in the analytical chemistry of Am.