Jh. Grinstead et al., CALIBRATION SOURCE FOR OH LASER-INDUCED FLUORESCENCE-DENSITY MEASUREMENTS WITH THERMALLY DISSOCIATED H2O IN ATMOSPHERIC AIR, Applied optics, 33(6), 1994, pp. 1115-1119
A calibration technique for OH laser-induced fluorescence (LIF) densit
y measurements through the use of the thermal dissociation of ambient
H2O in an atmospheric air furnace with a tunable KrF laser has been de
monstrated. The stable and uniform concentration of OH produced in the
furnace permits direct calibration of LIF signals without the uncerta
inties associated with reference flames. The presence of OH in atmosph
eric air that is heated to temperatures exceeding 1500 K is sufficient
for LIF measurements with most OH LIF laser systems. The measured OH
density is found to agree well with the computed OH chemical-equilibri
um density over a temperature range of 1500-1850 K.