A new technological approach makes fabrication of relief computer-gene
rated focusing elements for IR radiation by use of a dry photopolymer
recording material possible. The formation of a relief structure by se
lf-development takes place in the dark, subsequent to the holographic
illumination, without wet processing. Consequently these diffractive e
lements exhibit low surface scattering. The formation of a surface wav
e of the monomer along the light-darkness boundary is observed for the
first time to our knowledge and confirms the previously proposed ther
modynamic model of the mechanism of the hologram formation in photopol
ymerizable layers. Dye-sensitized polymerization of acrylamide is foun
d to produce nonlinearity of the relief recording. At least partial co
mpensation of this nonlinearity is attained by the introduction of app
ropriate corrections into the computer-generated amplitude function. A
diffraction efficiency of approximately 55% is obtained for CO2 laser
radiation (lambda = 10.6 mum).