We have detected single 650 nm photons with quantum efficiencies great
er than 60% using a large area silicon avalanche photodiode. We cool a
5 mm diam commercially available device to 100 K and operate in the g
ain-mode. For most applications-from the near-infrared to the ultravio
let-this device is the most sensitive photon counting detector that ha
s ever been demonstrated. In typical photon counting applications, thi
s detector should prove to be between two and one hundred times more s
ensitive than the best currently available devices.