We report the formation of two-dimensional foam and cluster structures
by spherical polystyrene particles trapped at the air/water interface
. The colloidal foam is a transient structure that evolves to the form
ation of clusters, but clusters can also be formed after deposition of
the sample. We also observed the formation of small aggregates, whose
formation along with the cluster stabilization can be explained in te
rms of a balance between electrostatic repulsive and van der Waals att
ractive interactions.