Ms. Anagnostou et al., ESTIMATION OF THE EXCHANGE CONSTANTS IN THE FE SUBLATTICE OF THE Y2FE17 AND Y2FE17N3-DELTA COMPOUNDS FROM THE ANALYSIS OF MOSSBAUER MEASUREMENTS, Journal of magnetism and magnetic materials, 130(1-3), 1994, pp. 57-62
From the analysis of Mossbauer data for Y2Fe17 and Y2Fe17N3-delta at v
arious temperatures the hyperfine fields for 4f, 6g, 12j, 12k iron sit
es were estimated as a function of temperature. The reduced magnetizat
ions calculated from the values of the hyperfine fields are fitted wit
h a mean field model for four interacting sublattices using a computer
program. The estimated exchange interaction from the fitting procedur
e between the 4f sites is found strongly negative (antiferromagnetic)
in Y2Fe17 whereas in Y2Fe17N3-delta it increases and becomes weak nega
tive following a modified Slater-Neel curve. The rest of the exchange
interactions are found positive or weak negative depending on the dist
ances between the Fe atoms.