Sc. Geiger et Rh. Loeppert, INFLUENCE OF AIR-DRYING AND SOIL GAS-PHASE CARBON-DIOXIDE ON DTPA-EXTRACTABLE IRON IN CALCAREOUS SOILS, Communications in soil science and plant analysis, 25(3-4), 1994, pp. 341-349
The extraction of a field-moist soil with DTPA will result in a level
of extractable iron (Fe) lower than that of the air-dried soil. Soil g
as-phase carbon dioxide (CO2) levels may be considerably higher than a
mbient atmospheric levels, especially in wet soils in the field. This
study was undertaken to determine whether gas-phase CO2 level influenc
es the quantity of Fe extracted by DTPA. Three moist calcareous soils
were incubated for 21 days, each at three different partial pressures
of CO2, after which the moist soils were extracted with DTPA. A sample
of each soil was also air dried, and was subsequently extracted with
DTPA. In each case, DTPA-extractable Fe from the moist sample was lowe
r than that from the air-dried sample; however, DTPA-extractable Fe in
creased with increasing CO2 partial pressure of in the moist soils. DT
PA-extractable Fe concentration for a given soil following air drying
was not significantly influenced by the CO2 partial pressure during in
cubation of the originally field-moist soil. DTPA-extract pH of the mo
ist soils followed the same trend as soil-solution pH (i.e., as CO2 co
ncentration of the soil gas-phase increased, soil solution pH and DTPA
extract pH both decreased); however, the slope of the pH versus log P
CO2 curve was less pronounced in the DTPA extract due to the buffering
capacity of the triethanolamine. From this study, it is concluded tha
t elevated soil gas-phase CO2 partial pressure does not contribute to
the lower level of DTPA-extractable Fe observed when the extraction is
performed on a field-moist versus an air-dried soil; increased C02 pa
rtial pressure actually resulted in a slight increase in concentration
of DTPA-extractable Fe obtained from a field-moist soil.