FLASH-PHOTOLYSIS OF THE BIS-U-OXO-BIS(L-C YSTEINE)-OXOMOLYBDENUM(V) IN AQUEOUS-SOLUTIONS

Authors
GONZALEZ MC FELIZ MR ZUBIMENDI JL BENITEZ G CAPPARELLI YAL
Citation
Mc. Gonzalez et al., FLASH-PHOTOLYSIS OF THE BIS-U-OXO-BIS(L-C YSTEINE)-OXOMOLYBDENUM(V) IN AQUEOUS-SOLUTIONS, Anales de quimica, 89(5-6), 1993, pp. 547-551
Citations number
33
Categorie Soggetti
Chemistry
Journal title
Anales de quimica → ACNP
ISSN journal
11302283
Volume
89
Issue
5-6
Year of publication
1993
Pages
547 - 551
Database
ISI
SICI code
1130-2283(1993)89:5-6<547:FOTBYI>2.0.ZU;2-8
Abstract
The flash photolysis of the bis-mu-oxo-bis(L-cisteine)-oxomolybdenum(V ) [Mo2O4(cis)2] in aqueous solutions at 25-degrees-C in the pH range 0 .5-2.0 in nitrogen atmosphere has been studied. Under the present expe rimental conditions a redox process is observed leading to Mo(VI) and H-2 as final products. Time resolved espectral analysis shows the form ation of two intermediaes, one absorbing at 400 nm, identified as mu-o xo-bis(oxo-aquo molybenum(V)), and other one showing a peak at 415 nm. The nature of both intermediates is discussed.